manganese and cobalt salts of para-amino-benzoic acid supported on silica gel as oxidizing catalysts
نویسندگان
چکیده
para-aminobenzoic acid is supported on silica gel via reaction of activated silica gel and p-aminobenzoic acid which is then converted to its manganese and cobalt salts. a mixture of the manganese and cobalt salts of the acid is used to catalyze allylic and benzylic alcohols to their corresponding carbonyl compounds in reasonable yields using oxygen or air. reactions are clean and the catalysts can be recovered easily and reused repeatedly.
منابع مشابه
Manganese and Cobalt Salts of Para-Amino-Benzoic Acid Supported on Silica Gel as Oxidizing Catalysts
Para-Aminobenzoic acid is supported on silica gel via reaction of activated silica gel and p-aminobenzoic acid which is then converted to its manganese and cobalt salts. A mixture of the manganese and cobalt salts of the acid is used to catalyze allylic and benzylic alcohols to their corresponding carbonyl compounds in reasonable yields using oxygen or air. Reactions are clean and the catal...
متن کاملAROMATIZATION OF 1 , CDIHYDROPYRIDINES WITH OXYGEN OR AIR USING MANGANESE AND COBALT SALTS OF p-AMINOBENZOIC ACID SUPPORTED ON SILICA GEL AS OXIDIZING CATALYSTS
Hantzsch 1,4-dihydropyridines are oxidized to the corresponding pyridine derivatives using oxygen or air and a mixture of the manganese and cobalt salts of parninobenzoic acid supported on silica gel as the catalysts. Reactions are clean and the catalysts can be recovered easily and reused repeatedly.
متن کاملaromatization of 1 , cdihydropyridines with oxygen or air using manganese and cobalt salts of p-aminobenzoic acid supported on silica gel as oxidizing catalysts
hantzsch 1,4-dihydropyridines are oxidized to the corresponding pyridine derivatives using oxygen or air and a mixture of the manganese and cobalt salts of parninobenzoic acid supported on silica gel as the catalysts. reactions are clean and the catalysts can be recovered easily and reused repeatedly.
متن کاملSelective Oxidation of Xylenes to Toluic Acids
A mixture of manganese, cobalt and lead para-amino benzoates supported on silica gel is used to catalyze oxidation of xylenes to toluic acids in presence of oxygen or air. Reactions are clean and catalysts can be recovered easily and reused.
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Nanostructured Mn oxide clusters supported on mesoporous silica KIT-6 efficiently evolve O(2) in aqueous solution under mild conditions.
متن کاملAg nanoparticle/melamine sulfonic acid supported on silica gel as an efficient catalytic system for synthesis of dihydropyrimidin thiones
3,4-dihydropyrimidin-2(1H)-thiones were synthesized in the presence of Ag nanoparticle/melamine sulfonic acid (MSA) supported on silica gel. The reaction was carried out at 110 oC for 20 min under solvent free conditions. In all cases, the three component reaction proceeded smoothly to give the corresponding 3,4-dihydropyrimidin-2(1H)-thiones in moderate to good yield. We have found the best co...
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عنوان ژورنال:
iranian journal of chemistry and chemical engineering (ijcce)ناشر: iranian institute of research and development in chemical industries (irdci)-acecr
ISSN 1021-9986
دوره 13
شماره 2 1994
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